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Metal-Air Battery breakthrough: Up to 11 times of Li-ion energy density

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2009-11-10 - cars21.com
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After most recent news about nickel-lithium batteries being three times better than li-ion, researchers at the Arizona State University might already dwarf these prospects by announcing a battery with 11 times the energy density of a lithium-ion battery at one-third the costs. The Metal-Air Ionic Liquid technology is supported by a 5 million US dollar research grant.
A University spin-off, namely Fluidic Energy, is testing a new battery technology that could have 11 times the energy density of a li-ion battery, while only costing less than one third and prolonging the battery life at the same time. Backed-up by a research grant from the US Department of Energy of about $5.13 million (around €3,4 million) the chances are pretty good to turn this ultra-dense energy storage technology into a reality.

Cody Friesen, a professor of materials science at Arizona State and founder of Fluidic Energy, said that the use of ionic liquids overcomes many of the problems that have held back metal-air batteries in the past. "I'm not claiming we have it yet, but if we do succeed, it really does change the way we think about storage," he added.

The wonder fluids that overcome the EV range problem?

Using ionic liquids as its electrolyte is the key of the new battery technology. The previous electrolytes used for metal-air batteries were water-based and caused therefore problems as the water evaporated and the batteries tended to fail prematurely. Another problem is that water has a relatively low electrochemical window, meaning it will begin to decompose when the cell exceeds 1.23 volts.

Ionic liquids that are used in the new Metal-Air Ionic Liquid batteries are salts that are a liquid at room temperature. The main advantages of ionic liquids are their non-volatility. In addition, they do not evaporate, they are physically stable, and they conduct electricity fairly well.

For the metal-air batteries it means first that they can function for a longer period time due to the non-evaporating electrolyte. Secondly, material with a greater energy density than for example zinc can be used thanks to its better electrochemical stability. And finally metal-air battery using an ionic liquid as its electrolyte would function significantly longer since drying out is no longer a problem.

Having electrochemical stability windows of up to five volts, that allows to go to much more energy-dense metals, the research team will target energy densities of at least 900 watt-hours per kilogram and up to 1,600 watt-hours per kilogram.

“This would mean that energy storage would no longer be a limiting factor for renewable energy, and electric vehicles that could travel 400 to 500 miles on a single charge at a cost just a little over lead-acid batteries," Friesen said.


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